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2-(diphenylphosphinoyl) pyrrolidines; versatile reagents for the synthesis of heterocyclic enamines and enamides.

✍ Scribed by B.H. Bakker; D.S. Tjin A-Lim; A. van der Gen


Book ID
104233778
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
188 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


A method is described for the preparation of N-substituted 2-(diphenylphosphinoyl) pyrrolidines. Application of these phosphine oxides in the Horner-Wittig reaction affords heterocyclic enamines and enamides in good yields.


πŸ“œ SIMILAR VOLUMES


N-methyl-N-anilinomethyl diphenylphosphi
✍ N.L.J.M. Broekhof; F.L. Jonkers; A. van der Gen πŸ“‚ Article πŸ“… 1980 πŸ› Elsevier Science 🌐 French βš– 212 KB

Cyclic as well as acyclic ketones, both saturated and a,b-unsaturated, can be converted into their homologous enamines by Horner-Wittig reaction with g-methyl-L-anilinomethyl diphenylphosphine oxide (3). Enamines are highly valued intermediates in organic synthesis. They react with a large variety

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v