2-Diphenylarsino-, 2-diphenylphosphinyl-, and 2-triphenylstannyl-derivatives of methyl 4,6-O-benzylidene-2-deoxy-α-d-altropyranoside. Crystal structure of the phosphinyl derivative
✍ Scribed by Martyn A. Brown; Philip J. Cox; R.Alan Howie; Olga A. Melvin; Oonah J. Taylor; James L. Wardell
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 587 KB
- Volume
- 498
- Category
- Article
- ISSN
- 0022-328X
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📜 SIMILAR VOLUMES
As part of a programme involving X-ray crystallographic studies" of cis-and tpuns-fused hexopyranosides, we now report on the crystal structures of methyl 2-~-methyl-~-D-glucop~anoside\* (11, which was obtained by debe~lidenation of methyl 4,~-O-benzyIidene-2-O-methyI-3-O-~-tolylsulfonyl-~-~-glucopy
Acylated ]3-o-xylopyranose derivatives are known to exist as a mixture of the 1C 4 and 4C I conformers in rapid equilibrium in solution [3]. Several conformations have also been reported for/3-D-xylopyranose derivatives in the solid state [4]. In the course of our study to investigate the functions