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2-(Diethylamino)ethanethiol, a New Reagent for the Odorless Deprotection of Aromatic Methyl Ethers.

✍ Scribed by Javier Magano; Michael H. Chen; Jerry D. Clark; Thomas Nussbaumer


Publisher
John Wiley and Sons
Year
2007
Weight
25 KB
Volume
38
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


Trichloro(methyl)silane/Sodium Iodide, A
✍ Prof. Dr. George A. Olah; Altaf Husain; Dr. B. G. Balaram Gupta; Dr. Subhash C. πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 244 KB

**More than a dozen examples verify that ethers are cleaved regioselectively in very good yields by MeSiCl~3~/NaI in acetonitrile;** primary and secondary methyl‐, benzyl‐, trityl‐ and tetrahydropyranyl ethers directly afford the primary and secondary alcohols. In the case of __tert__‐alkylmethyl et