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2-Cyano-6-(trifluoromethyl)-4H-pyran-4-one: A novel versatile CF3-containing building block

✍ Scribed by Boris I. Usachev; Dmitrii L. Obydennov; Gerd-Volker Röschenthaler; Vyacheslav Ya. Sosnovskikh


Book ID
113711628
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
314 KB
Volume
137
Category
Article
ISSN
0022-1139

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2,3-dihydro-3,5-dihydroxy-6-methyl-4H-py
✍ F.D. Mills; D. Weisleder; J.E. Hodge 📂 Article 📅 1970 🏛 Elsevier Science 🌐 French ⚖ 202 KB

In an extension of our studies on the thermal decomposition of Amadori compounds (l), we have identified 2,3-dihydro-3,5-dihydroxy-6-methyl-4&pyran-4-one (Ia) as the major solid product that is volatilized during the pyrolysis of l-deoxy-l-(k-prolino)-&fructose at 138"/1 mm. The structural assignmen