In the crystal structure of the title compound, C 11 H 10 N 3 O 4 S + Á-Cl À Á0.5H 2 O, there are two formula units in the asymmetric unit. A network of N-HÁ Á ÁCl, N-HÁ Á ÁO and O-HÁ Á ÁCl hydrogen bonds helps to establish the crystal packing. The nitro group of one of the organic cations is disord
2-Carboxy-4-(hydroxymethyl)pyridinium chloride hemihydrate
✍ Scribed by Chrzanowski, Lars S. von ;Lutz, Martin ;Spek, Anthony L. ;McDonald, Aidan R. ;Klink, Gerard P. M. van ;Koten, Gerard van
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 213 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C~7~H~8~NO~3~
^+^·Cl^−^·0.5H~2~O, features inter- and intramolecular O—H...Cl and N—H...O hydrogen bonds, linking the molecules into a three-dimensional network. The water molecule is located on a crystallographic twofold rotation axis.
📜 SIMILAR VOLUMES
Dihydroxy-2-(hydroxymethyl)propan-2ylamino]methylene}-2-methoxy-4-{(E)-[3-(trifluoromethyl)phenyl]diazenyl}cyclohexa-2,4-dienone Cem Cu ¨neyt Ersanlı, a \* C ¸ig ˘dem Albayrak, b Mustafa Odabas ¸og ˘lu b and Canan Kazak a
In the title compound, C~5~H~6~N^+^·C~8~H~4~NO~6~ ^−^, N—H...O and O—H...O hydrogen bonds stabilize the crystal structure.
The title salt, C~8~H~20~NO~5~ ^+^·C~7~H~4~NO~4~ ^−^·H~2~O, is composed of a 4-nitrobenzoate anion, a [2-hydroxy-1,1-bis(hydroxymethyl)ethyl]bis(2-hydroxyethyl)ammonium (NBHHP) cation and a water molecule. The three units are linked by O—H...O hydrogen bonds.
Cl À Á2H 2 O, both the cation and anion lie on special positions of site symmetry 2. The cation and anion, along with the water molecules of crystallization, are linked into a three-dimensional network by extensive hydrogen bonds.