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2′-Benzo­yl-1′-(4-chloro­phen­yl)-5′,6′,7′,7a′-tetra­hydro­spiro­[indan-2,3′(2′H)-1H-pyrrolizine]-1,3-dione

✍ Scribed by Kalyanasundaram, S. ;Selvanayagam, S. ;Velmurugan, D. ;Ravikumar, K. ;Poornachandran, M. ;Raghunathan, R.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
494 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, C 28 H 22 ClNO 3 , has two crystallographically independent molecules in the asymmetric unit. The pyrrolidine ring (A) of the pyrrolizine system adopts an envelope conformation in both molecules, whereas the other five-membered ring (B) adopts an envelope conformation in one molecule and a twist conformation in the other. The molecular packing is stabilized by intermolecular C-HÁ Á ÁO, C-HÁ Á Á andinteractions.


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Methyl 1′-(2-hydr­oxy-1,3-dioxo-2,3-dihy
✍ Kumar, B. K. Satis ;Gayathri, D. ;Velmurugan, D. ;Ravikumar, K. ;Ramesh, E. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 291 KB

The two pyrrolidine rings in the title compound, C~25~H~22~N~2~O~6~, adopt envelope conformations. Molecules are stabilized by intramolecular O—H...O hydrogen bonds, and linked into centrosymmetric dimers by intermolecular N—H...O hydrogen bonds.