Nucleophilic aldition of u cyanide anion to 2-benwpyryliwn salt8 I takes place at the firet position end led8 to stable i8ochzvmene8 II, which are oxygen anabgs of Reissert aqXUnd8. The structure II uaa a~nfirmed by IR, 'H-NM? and '3C-NMR spectra. The tatter epectra reveal clearly the cyarr, gzup (w
2-benzopyrylium salts. 45. Interaction of 2-benzopyrylium salts and their monocyclic analogs with imines of ketones
✍ Scribed by D. É. Tosunyan; S. V. Verin; E. V. Kuznetsov
- Publisher
- Springer US
- Year
- 1994
- Tongue
- English
- Weight
- 640 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0009-3122
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📜 SIMILAR VOLUMES
The weak intensity of the CN stretching band in IR spectra for l-ayanoiso chromenes is obviousZy determined by the steric position of the CN group in the rroZecuZe, as it was estabUshed by X-ray structuraZ anclysis for the ayanide addition product (2d) of l-isopropyZ-3-methyZ-2-benzopyryZium sclts.
The footnote is marked with an asterisk after the only text's mention of the reference 1141: . . . and the only example of 1 -cyano-1 -IV-R-amidoisochromenes [ 141. + \*Nevertheless the sharp CN stretching band at 2230 cm-' can be discovered in cyanoisochromenes II a-h after an accumulation and a sc