3-Carboxy-2-benzopyrylium salts form 3-carboxyisoquinolinium salts, their decarboxylated analogs, or products of contraction of the heterocycle, namely, cyclic ketols, depending on the nature of the amine and solvent. Upon treatment with acids, these ketols are demethylated through the intermediate
✦ LIBER ✦
2-Benzopyrylium salts. 42. Ortho-quinoid intermediates in recyclization reactions of 2-benzopyrylium salts
✍ Scribed by S. V. Verin; D. É. Tosunyan; E. V. Kuznetsov
- Publisher
- Springer US
- Year
- 1991
- Tongue
- English
- Weight
- 526 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0009-3122
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The weak intensity of the CN stretching band in IR spectra for l-ayanoiso chromenes is obviousZy determined by the steric position of the CN group in the rroZecuZe, as it was estabUshed by X-ray structuraZ anclysis for the ayanide addition product (2d) of l-isopropyZ-3-methyZ-2-benzopyryZium sclts.