2-Benzopyrylium salts. 27. Some transformations of 6-oxodibenzo[a,g]-quinolizinium salts
β Scribed by I. V. Shcherbakova; O. E. Shelepin; N. A. Klyuev; G. N. Dorofeenko; E. V. Kuznetsov
- Book ID
- 112345961
- Publisher
- Springer US
- Year
- 1982
- Tongue
- English
- Weight
- 581 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0009-3122
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π SIMILAR VOLUMES
3-Carboxy-2-benzopyrylium salts form 3-carboxyisoquinolinium salts, their decarboxylated analogs, or products of contraction of the heterocycle, namely, cyclic ketols, depending on the nature of the amine and solvent. Upon treatment with acids, these ketols are demethylated through the intermediate
## Abstract The synthesis of a series of substituted 6aβazonia[5]helicene salts 3dβj and 12aβazoniabenzo[__ghi__]perylene salts 4d and 4g by photocyclization of the corresponding 2βstyrylbenzo[__a__]βquinolizinium derivatives 2dβj is described. The product ratios of 3dβj and 4dβj depend on the ster