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2-Amino-4-(2-pyridyl)thiazole as Chelating Ligand: A Dinuclear Oxido-Bridged Ferric Complex and Mononuclear 3d Metal Complexes

✍ Scribed by Huxel, Timo; Leone, Selina; Lan, Yanhua; Demeshko, Serhiy; Klingele, Julia


Book ID
123614600
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
652 KB
Volume
2014
Category
Article
ISSN
1434-1948

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✍ Roland Krämer; Kurt Polborn; Christian Robl; Wolfgang Beck 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 606 KB

## Elimination of chloride from Cp\*Rh(L-PheO)Cl with AgBF, leads to the trinuclear complex [Cp\*Rh(p-L-Phe0)],3+(BF4-)3 (Z), in which the amino acidate acts both as an (N, 0)-chelating and as a carboxylate bridging ligand according to the X-ray structural determination. Trimerization of [Cp\*Rh(P