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2-Amino-1,1,3-tricyanopropene: A new inhibitor of oxygen evolution in photosynthesis

✍ Scribed by A.A. Horton; D.O. Hall


Book ID
115714815
Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
188 KB
Volume
131
Category
Article
ISSN
0005-2728

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A new enamine reaction: synthesis of 3-a
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Cyclohexanone enamines react with dibenzoyldiimide (IIa) at room temperature leading to a I:1 addition product in almost quantitative yield. This adduct, on mild acidic hydrolysis, gives 2-(N,N'-dibenzoyl)hydrazinccyclohexanone (IVa), identical with that obtained from cyclohexanone and (IIa) at lOOa