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2-Acetoxy-2-Acetylaminohexafluoropropane and its reactions

✍ Scribed by I. L. Knunyants; Yu. V. Zeifman; N. P. Gambaryan

Book ID
112420029
Publisher
Springer
Year
1966
Tongue
English
Weight
224 KB
Volume
15
Category
Article
ISSN
1573-9171

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## Abstract The photoaddition, hydrolysis, retro‐aldol sequences **1 β†’ 2 β†’ 3** and **4 β†’ 5 + 6 β†’ 7** proceeded in high yield and in a regiospecific manner. However, the enol acetate **8** on irradiation furnished the tricyclic ketoacetate **9** as the major product, presumably by a hydrogen shift i