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2-(5,7-Dibromoquinolin-8-yloxy)-N,N-diphenylacetamide

✍ Scribed by Bi, Sai ;Wu, Xiao-Hui ;Tang, Xiao-Fang ;Wen, Yong-Hong


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
831 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, C 23 H 16 Br 2 N 2 O 2 , intramolecular C-HÁ Á ÁBr and C-HÁ Á ÁN hydrogen bonds from the quinoline fragment form two five-membered rings. The quinoline ring system makes dihedral angles of 81.6 (2) and 31.2 (2) with the phenyl rings of the diphenylacetamide fragment. In the crystal structure, molecules are linked into chains along the b axis by intermolecular C-HÁ Á ÁO hydrogen bonds.

Related literature

For background to the applications of 8-hydroxyquinoline and its derivatives, see:


📜 SIMILAR VOLUMES


2-(5,7-Dichloroquinolin-8-yloxy)-N,N-dip
✍ Tang, Xiao-Fang ;Wen, Yong-Hong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 940 KB

In the title compound, C 23 H 16 Cl 2 N 2 O 2 , intramolecular C-HÁ Á ÁCl and C-HÁ Á ÁN hydrogen bonds from the quinoline fragment form five-and six-membered rings, respectively. The quinoline ring system makes dihedral angles of 30.42 (1) and 81.17 (1) with the phenyl rings of the diphenylacetamide

N,N-Dicyclohexyl-2-(5,7-dibromoquinolin-
✍ Liu, Jian-Fei ;Tang, Xiao-Fang ;Wen, Yong-Hong 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 766 KB

In the title compound, C~23~H~28~Br~2~N~2~O~2~, all bond lengths and angles are within normal ranges. The two cyclohexyl groups adopt the normal chair conformation. The sum of the angles around the amide N and C atoms are both 360°, implying a planar configuration. The crystal packing is stabilized

Bis[N-(5,7-dibromo­quinolin-8-yl)-3,5-bi
✍ Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 423 KB

In the title compound, [Zn(C 17 H 7 Br 2 F 6 N 2 O 2 S) 2 ], the zinc(II) ion has a distorted tetrahedral geometry formed by the N atoms of the quinoline and the sulfonamide groups. One intermolecular C-HÁ Á ÁO hydrogen bond to a sulfonyl O atom is observed.

N-(2-Chloro­phen­yl)-2-(quinolin-8-yl­ox
✍ Zhang, Shu-Sheng ;Xu, Li-Li ;Wen, Hui-Ling ;Li, Xue-Mei ;Wen, Yong-Hong 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 114 KB

In the title compound, C~17~H~14~ClN~2~O~3~, there are intramolecular hydrogen bonds of types N—H...O (2.634 and 2.570 Å), N—H...Cl (2.925 Å) and C—H...O (2.894 Å). The dihedral angle between the planes of the quinoline system and the benzene ring is 20.3 (1)°. The crystal packing is stabilized by π

N-(Quinolin-8-yl)-2-(quinolin-8-yl­oxy)a
✍ Wen, Yong-Hong ;Xu, Li-Li ;Bi, Sai ;Zhang, Shu-Sheng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 189 KB

In the crystal structure of the title compound, C 20 H 15 N 3 O 2 , molecules are linked into dimers by C-HÁ Á ÁO intermolecular hydrogen bonds. The crystal packing is also stabilized by C-HÁ Á Á andinteractions involving the quinoline units.