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2-(4-methylpyridin-2-yl)-1H-benzimidazole derivatives. Part I. X-Ray structural analysis

✍ Scribed by Giuliana Gervasio; Domenica Marabello; Claudia Barolo; Pierluigi Quagliotto; Guido Viscardi


Book ID
102339972
Publisher
Journal of Heterocyclic Chemistry
Year
2003
Tongue
English
Weight
58 KB
Volume
40
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

The X‐ray analyses of some neutral and cationic derivatives of 2‐(4‐methylpyridin‐2‐yl)‐1__H__‐benzimida‐zole are reported and the structural data tentatively correlated to relative UV‐visible properties. A rotation of the γ‐picoline ring with respect to the benzimidazole moiety may be responsible of the spectral behavior.


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2-(4-methylpyridin-2-yl)-1H-benzimidazol
✍ Ermanno Barni; Claudia Barolo; Pierluigi Quagliotto; Piero Savarino; Guido Visca 📂 Article 📅 2003 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 66 KB

## Abstract A selected series of 2‐(4‐methylpyridin‐2‐yl)‐1__H__‐benzimidazole derivatives, bases and cyclic mono‐ and bis‐salts, were synthesized. Complete ^'1^H nmr characterization is reported. Ambiguous assignments were solved using ^1^H‐^1^H NOESY analysis. Significant ir and ^1^H nmr data are