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2-(4-Fluorophenyl)-6-phenyltetrahydro-2H-thiopyran-4-one 1-oxide

✍ Scribed by Thiruvalluvar, A. ;Balamurugan, S. ;Butcher, R. J. ;Pandiarajan, K. ;Devanathan, D.

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 319 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807053111

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✦ Synopsis

In the title compound, C~17~H~15~FO~2~S, a crystallographic mirror plane bisects the molecule, passing through O=S and C=O of the central ring, with statistical disorder of the F atom. Orientational disorder of the aromatic ring is also observed; the site occupancy factors are ca. 0.75 and 0.25. In the molecule, the thiopyran unit has a chair conformation; the geometries around the S and carbonyl C atoms are tetrahedral and planar, respectively.

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