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2 + 2 + 2 Cycloaddition vs Radical Ion Chemistry in the Photoreactions of 1,2,4,5-Benzenetetracarbonitrile with Alkenes in Acetonitrile

✍ Scribed by Vanossi, Matteo; Mella, Mariella; Albini, Angelo

Book ID
126086937
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
819 KB
Volume
116
Category
Article
ISSN
0002-7863

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Solvent Effects in [4+2] Cycloadditions
Solvent Effects in [4+2] Cycloadditions of Polyhalogenated Cyclopentadienes with 4-Phenyl-1,2,4-triazoline-3,5-dione
✍ Sauer, JΓΌrgen ;Schuhbauer, Hans Markus πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 497 KB

## Abstract Relative rates of [4 + 2] cycloadditions of cyclopentadienes 1a–1e with 4‐phenyl‐1,2,4‐triazoline‐3,5‐dione (2) in 12 different solvents vary by factors of up to 19000, but the reactions show similar solvent effects. Rate constants __k__~2~ correlate well with solvent parameters __AN__