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2′-(1,3-Benzodioxol-5-ylmethyl­ene)-2-methoxy­benzohydrazide

✍ Scribed by Jing, Zuo-Liang ;Yu, Ming


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
265 KB
Volume
63
Category
Article
ISSN
1600-5368

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2′-(1,3-Benzodioxol-5-ylmethyl­ene)furan
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In the title molecule, C 13 H 10 N 2 O 4 , the dihedral angle between the benzodioxole ring system and the furan ring is 18.7 (1) . Intermolecular N-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds link the molecules into a three-dimensional framework.

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Crystals of the title compound, C 15 H 15 NO 3 , were obtained from a condensation reaction of piperonal with 1-azabicyclo[2.2.2]octan-3-one and subsequent crystallization of the product from ethyl acetate. The geometry about the C C double bond connecting the 1,3-benzodioxole moiety to the azabicyl