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2-[(1-Imidazolyl)formyloxy]ethyl methacrylate as a new chemical precursor of functional polymers

✍ Scribed by Elisabetta Ranucci; Gloria Spagnoli; Paolo Ferruti

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
60 KB
Volume
20
Category
Article
ISSN
1022-1336

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✦ Synopsis

A novel activated derivative of methacrylic acid, namely 2-[(1-imidazolyl)formyloxy]ethyl methacrylate was synthesized and homopolymerized. The resulting polymer was used in exchange reactions with alcohols and amines, thus showing a potential for the synthesis of multifunctional polymers. All reactions, expecially those carried out in the presence of amines, proceeded under mild conditions. 2-[(1-Imidazolyl)formyloxy]ethyl methacrylate can also be regarded as a valuable precursor for the preparation of new and easily polymerizable functional monomers.

📜 SIMILAR VOLUMES

2-[(1-Imidazolyl)formyloxy]ethyl Methacr
2-[(1-Imidazolyl)formyloxy]ethyl Methacrylate as Selective Methacryloylating Agent: Kinetics of Reaction with Model Alcohols and Amines
✍ Elisabetta Ranucci; Michela Grigolini; Paolo Ferruti 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB

## Abstract The kinetics of the coupling reactions of 2‐[(1‐imidazolyl)formyloxy]ethyl methacrylate (HEMA‐Im) with model primary and secondary alcohols and amines have been investigated both in the absence and in the presence of imidazole and triethylamine as catalysts. In the absence of added cata