1/η expansion for the binding energies of finite-depth potentials
✍ Scribed by M. Bag; M.M. Panja; R. Dutt; Y.P. Varshni
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 357 KB
- Volume
- 222
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
We present a systematic perturbative method for calculating the binding energies of ro-vibrational quantum states for a finite depth potential. Using an asymptotic expansion in powers of 1 /q, where q is the dimensionless physical depth parameter, explicit calculations are performed. Our analytic results lead to highly convergent series for the binding energies, and numerical results for realistic potentials such as Morse and Lennard-Jones potentials are found to be in excellent agreement with the exact ones.
📜 SIMILAR VOLUMES
The ionization potentials and binding energies of gold and silver clusters and their positive ions containing up to four atoms are investigated using a complete active space MCSCF followed by multi-reference singles+doubles CI which included up to 1.9 million conf~urations. The ionization potential
Potrntial energy surfxcs were obtained in an estendcd IIi.ickel culculaGon for the lowest ' A1 und ' 82 states of the ferrous porphin-CO compiles. The relcv~nce of these surfaces to cspcrimental kinetic data is discussed.