**(+)‐(1__S__, 3__S__, 6__S__, 8__S__)‐ and (−)‐(1__R__, 3__R__, 6__R__, 8__R__)‐2,7‐dioxa‐twista‐4,9‐diene.** A synthesis and the determination of the sense of chirality of (+)‐(1__S__, 3__S__, 6__S__, 8__S__)‐ and (−)‐(1__R__, 3__R__, 6__R__, 8__R__)‐2,7‐dioxa‐twista‐4,9‐diene ((+)‐**5** and (−)‐
(+)-(1S, 3S, 6S, 8S)-und (−)-(1R, 3R, 6R, 8R)-4, 9-Twistadien: Synthese und Bestimmung der absoluten Konfiguration
✍ Scribed by Hans-Georg Capraro; Camille Ganter
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- German
- Weight
- 324 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
(+)‐(1__S__, 3__S__, 6__S__, 8__S__)‐and (−)‐(1__R__, 3__R__, 6__R__, 8__R__)‐4, 9‐Twistadiene: Synthesis and Absolute Configuration
A synthesis and the determination of the absolute configuration of (+)‐(1__S__, 3__S__, 6__S__, 8__S__)‐ and (−)‐(1__R__, 3__R__, 6__R__, 8__R__)‐4, 9‐twistadiene ((+)‐ and (−)‐4, respectively) is described. Their chiroptical properties are compared with those of saturated twistane ((+)‐ and (−)‐5) as well as with those of the unsaturated and saturated 2, 7‐dioxatwistane analogs (+)‐ and (−)‐9, and (+)‐ and (−)‐10, respectively, which also are compounds of known absolute configurations.
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