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(+)-(1S, 3S, 6S, 8S)-und (−)-(1R, 3R, 6R, 8R)-4, 9-Twistadien: Synthese und Bestimmung der absoluten Konfiguration

✍ Scribed by Hans-Georg Capraro; Camille Ganter


Publisher
John Wiley and Sons
Year
1980
Tongue
German
Weight
324 KB
Volume
63
Category
Article
ISSN
0018-019X

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✦ Synopsis


(+)‐(1__S__, 3__S__, 6__S__, 8__S__)‐and (−)‐(1__R__, 3__R__, 6__R__, 8__R__)‐4, 9‐Twistadiene: Synthesis and Absolute Configuration

A synthesis and the determination of the absolute configuration of (+)‐(1__S__, 3__S__, 6__S__, 8__S__)‐ and (−)‐(1__R__, 3__R__, 6__R__, 8__R__)‐4, 9‐twistadiene ((+)‐ and (−)‐4, respectively) is described. Their chiroptical properties are compared with those of saturated twistane ((+)‐ and (−)‐5) as well as with those of the unsaturated and saturated 2, 7‐dioxatwistane analogs (+)‐ and (−)‐9, and (+)‐ and (−)‐10, respectively, which also are compounds of known absolute configurations.


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