𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1H NMR of probes oriented in stretched polyethylene

✍ Scribed by Antti Kivinen; Martti Ovaska; Kari Soljamo


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
316 KB
Volume
128
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


H NMR spectra of some mmllmolecules oriented in stretched polyethylene rods have been recorded. The band splitting due to direct dipole-dipole couplings is obtained and the corresponding orientation parameters are shown as a function of the draw ratio of the polymer and the temperature. This method is compared to that of using liquid crystals as the orienting solvent.


πŸ“œ SIMILAR VOLUMES


NMR studies of molecular mobility in uni
✍ Egorov, E. A. ;Zhizhenkov, V. V. πŸ“‚ Article πŸ“… 1982 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 943 KB

## Abstract The effect of elasticlike uniaxial tension on molecular mobility in polymers have been studied over a wide temperature range using the broad‐line NMR technique. The studies were carried out on oriented semicrystalline samples of nylon 6, poly(ethylene terephthlate), polypropylene, polye

Triplet-state ESR spectra of aromatic mo
✍ I.M. Brown; P.J. Phillips; D. Parikh πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 267 KB

Triplet-state ESR spectra show that when the aromatic molecules anthracene, anthracene-d,,,, terphenyl, and acridine are dissolved m stretched, low-density polyethylene films, a fraction of these solute molecules become oriented with their X axis along the stretch direction but with their XY planes