1H NMR of probes oriented in stretched polyethylene
β Scribed by Antti Kivinen; Martti Ovaska; Kari Soljamo
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 316 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
H NMR spectra of some mmllmolecules oriented in stretched polyethylene rods have been recorded. The band splitting due to direct dipole-dipole couplings is obtained and the corresponding orientation parameters are shown as a function of the draw ratio of the polymer and the temperature. This method is compared to that of using liquid crystals as the orienting solvent.
π SIMILAR VOLUMES
## Abstract The effect of elasticlike uniaxial tension on molecular mobility in polymers have been studied over a wide temperature range using the broadβline NMR technique. The studies were carried out on oriented semicrystalline samples of nylon 6, poly(ethylene terephthlate), polypropylene, polye
Triplet-state ESR spectra show that when the aromatic molecules anthracene, anthracene-d,,,, terphenyl, and acridine are dissolved m stretched, low-density polyethylene films, a fraction of these solute molecules become oriented with their X axis along the stretch direction but with their XY planes