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1H NMR detection of CoOH2 .dblharw. CoOH interconversions in high-spin cobalt(II) complexes

✍ Scribed by Bertini, Ivano.; Canti, Giorgio.; Luchinat, Claudio.; Messori, Luigi.


Book ID
126873081
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
502 KB
Volume
21
Category
Article
ISSN
0020-1669

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## Abstract An Fe(II) complex with Z‐Ala‐CysProLeuCysGlyNHC~6~H~4~__m__F (Z = benzoxylcarbonyl) having an invariant bidentate peptide ligand, CysKYCys, in rubredoxins was synthesized. The contact‐shifted ^1^H, ^2^H and ^19^F NMR signals of (Et~4~N)~2~[Fe(ZAlacysProLeucysGlyNHC~6~