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1H NMR and electrochemical studies on iron-sulfur interconversions and mixed metal cluster formation

✍ Scribed by A.L. Macedo; C. Moreno; I. Moura; J. LeGall; J.J.G. Moura


Book ID
103568413
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
64 KB
Volume
43
Category
Article
ISSN
0162-0134

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## Abstract 1D and 2D ^1^H NMR studies are reported on the oxidized and reduced [4Fe‐4S] cluster of __Desulfovibrio gigas__ ferredoxin I (Fdl). Several low‐field contact shifted resonances (fast relaxing) are assigned to β‐CH~2~ and α‐CH coordinated cysteinyl residues. NOESY patterns (supported by