(1H-Benzotriazole-κN3)trichlorocobalt(III)–1H-benzotriazole–water (1/1/1)
✍ Scribed by Zhang, Ze-Feng ;Li, Li-Xin ;Wang, Xiao-Qing ;Xie, Cheng-Zhi ;Wang, Ru-Ji ;Shen, Guang-Qiu
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 393 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.045 wR factor = 0.110 Data-to-parameter ratio = 13.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title mononuclear complex, [Fe(C 6 H 5 N 3 O) 6 ](ClO 4 ) 3 Á-2C 2 H 3 N, the Fe III ion shows a close-to-ideal octahedral geometry coordinated by six O atoms from six 1-hydroxybenzotriazole ligands. The ligand benzotriazole exists as a zwitterion.
In the title compound, C 15 H 12 ClN 3 O, the molecules are linked into centrosymmetric dimers by C-HÁ Á ÁO intermolecular hydrogen bonds. The molecular packing is further stabilized byinteractions.