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1H and 13C NMR study of the complex formed by copper(II) with the nucleoside antibiotic sinefungin

✍ Scribed by Massimo Cappannelli; Elena Gaggelli; Małgorzata Jeżowska-Bojczuk; Elena Molteni; Ariel Mucha; Elena Porciatti; Daniela Valensin; Gianni Valensin

Book ID
108175018
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
760 KB
Volume
101
Category
Article
ISSN
0162-0134

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✍ Rainer Benken; Harald Günther 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 532 KB

Dilithium naphthalene (2) and its TMEDA complex 3 have been prepared, and their 'Hand I3C-NMR spectra were analyzed in terms of chemical shifts and coupling constants. From its Q value, 2 is characterized as delocalized [4n] B system and the 'H-as well as the 6Li-NMR shifts classify the ion as stron