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1H and 13C NMR structure determination of a new stereoisomer of isoreserpiline pseudoindoxyl from Rauvolfia grandiflora

✍ Scribed by N. M. Cancelieri; I. J. Curcino Vieira; L. Mathias; R. Braz-Filho

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 104 KB
Volume: 41
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1168

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✦ Synopsis

Abstract

An NMR study of a new stereoisomer of isoreserpiline pseudoindoxyl alkaloid is described. The complete ^1^H and ^13^C NMR assignments of the compound were carried out using COSY, HMQC and HMBC. Stereochemistry at carbons C‐2, C‐3, C‐15, C‐20 and C‐19 was established using values of ^1^H chemical shifts, coupling constants and NOESY experiments. Copyright © 2003 John Wiley & Sons, Ltd.

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