𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1H and 13C NMR signal assignments of carboxyl-linked glucosides of bile acids

✍ Scribed by Takashi Iida; Genta Kakiyama; Akari Shimada; Kumiko Mushiake; Nariyasu Mano; Junichi Goto; Toshio Nambara

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
140 KB
Volume
41
Category
Article
ISSN
0749-1581

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Complete ^1^H and ^13^C resonance assignments were carried out for a new type of carboxyl‐linked glucosides of chenodeoxycholic (3α,7α‐dihydroxy‐5β‐cholan‐24‐oic) and hyodeoxycholic (3α,6α‐dihydroxy‐5β‐cholan‐24‐oic) acids by using several homonuclear (^1^H–^1^H) and heteronuclear (^1^H–^13^C) 2D NMR techniques. Differences in the ^1^H and ^13^C resonances between the α‐ and β‐anomers of the ester glucosides of bile acids were clarified for the first time. A comparison of the ^1^H and ^13^C signal shifts induced by β‐D‐glucosidation at the 24‐carboxyl and 3α‐hydroxyl groups in the parent 5β‐cholanoic acid was also made. Copyright © 2003 John Wiley & Sons, Ltd.

📜 SIMILAR VOLUMES

Complete 1H and 13C NMR assignments of t
Complete 1H and 13C NMR assignments of the epimeric menthane-1-carboxylic acids
✍ Debra K. Dillner; Daniel D. Traficante 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB

## Abstract Complete NMR analyses with full assignments for ^1^H and ^13^C NMR spectral data for both epimers of menthane‐1‐carboxylic acid are described. The NMR properties of the recently synthesized axial isomer had not been previously described, and through use of a variety of 1D and 2D techniq

Complete 1H and 13C NMR assignments of s
Complete 1H and 13C NMR assignments of sesquiterpene glucosides from Ixeris sonchifolia
✍ ZeyEi Na; Jeong-Yong Cho; Hyoung Jae Lee; Jin Ho Chung; Ki Deok Park; Young Ju L 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 167 KB 👁 1 views

## Abstract Four sesquiterpene glucosides were isolated from __Ixeris sonchifolia__ Hance. The structure of a new compound (1) was assigned as 9β‐monohydroxy‐2,12‐dioxo‐guaia‐3,11(13)‐dien‐1α,5α,6β,7α,9β,10αH‐12,6‐olide‐9‐__O__‐β‐D‐ glucopyranoside (ixerinoside). In addition, unambiguous and comple

13C and 1H NMR signal assignments of som
13C and 1H NMR signal assignments of some new synthetic dehydroabietic acid derivatives
✍ Marinaldo S. de Carvalho; Lúcia H. B. Baptistella; Paulo M. Imamura 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 124 KB 👁 1 views

## Abstract The ^1^H and ^13^C NMR signal assignments of a series of new synthetic derivatives of dehydroabietic acid are presented. Copyright © 2008 John Wiley & Sons, Ltd.

Assignment of 1H and 13C NMR signals of
Assignment of 1H and 13C NMR signals of eight apocampholenic derivatives
✍ M. Findeisen; C. Prehn; L. Hennig; K. Schulze 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 2 views

The 1H and 13C chemical shifts of four apocampholenic aldehydes and the corresponding alcohols are reported. 1998 John ( Wiley & Sons, Ltd.

Assignment of the 1H and 13C NMR signals
Assignment of the 1H and 13C NMR signals of some benzofurocoumarins
✍ Elías Quezada; Lourdes Santana; Eugenio Uriarte 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 86 KB 👁 1 views

## Abstract The complete ^1^H and ^13^C NMR assignment of four **6**,**7**‐benzo‐fused furocoumarins (**1**–**4**) and three 3,4‐benzo‐fused furocoumarins (**5**–**7**) has been performed using 1D and 2D NMR techniques, including COSY, HMQC and HMBC experiments. Copyright © 2006 John Wiley & Sons,