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1H and 13C NMR assignments of the antitumor macrolide bryostatin 1

✍ Scribed by Daniel E. Schaufelberger; Gwendolyn N. Chmurny; Mary P. Koleck

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 610 KB
Volume: 29
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260290414

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✦ Synopsis

Abstract

During a large‐scale isolation of bryostatin 1, NMR measurements indicated that parts of the published ^13^C and ^1^H NMR assignments had to be revised. These reassignments were based on extensive homonuclear and heteronuclear one‐ and two‐dimensional NMR techniques performed at 500 MHz. These independently obtained assignments are also in good agreement with the revised assignments and structure of bryostatin 3.

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