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1H-13C CPMAS and T2 Relaxation Solid-State NMR Measurements of Melamine-Based Polycondensed Chemical Gels

✍ Scribed by Chrystelle C. Egger; Volker Schädler; Jérôme Hirschinger; Jésus Raya; Burkhard Bechinger


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
54 KB
Volume
208
Category
Article
ISSN
1022-1352

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1H-13C CPMAS and T2 Relaxation Solid-Sta
✍ Chrystelle C. Egger; Volker Schädler; Jérôme Hirschinger; Jésus Raya; Burkhard B 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 298 KB

## Abstract Gel networks prepared from aqueous melamine‐formaldehyde resins via a sol–gel route were characterised by ^13^C CPMAS (where MAS stands for magic angle spinning)‐NMR and __T__~2~ relaxation. We show that within the aqueous networks, the type and amount of functional groups on the melami

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## Abstract A combination of solid‐state ^13^C CP/MAS NMR methods was used to study the rates of rotation of the phenyl group in 3,5‐dimethyl‐1‐phenylhex‐1‐yn‐3‐ol. The methods used were __T__~1ρ~ measurements, lineshape analysis and 2D exchange spectroscopy over the temperature range 219–284 K. Th