1H, 13C and 17O NMR spectral studies on monocyclic dioxolanes, dioxanes, dioxepanes and dioxocanes and cycloalkane-fused (5–8-membered) bicyclic 1,3-dioxolanes and 1,3-dioxanes
✍ Scribed by Kalevi Pihlaja; Heli Nummelin; Karel D. Klika; József Czombos
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 193 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.869
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✦ Synopsis
Abstract
^1^H, ^13^C and ^17^O NMR data for a set monocyclic dioxolanes, dioxanes, dioxepanes, and dioxocanes and cycloalkane‐fused (5–8‐membered) bicyclic 1,3‐dioxolanes and 1,3‐dioxanes comprising 81 compounds in all are presented. This systematic configurational and conformational study addresses the deficiency in the available data regarding the conformational behaviour and, in particular, the scant ^17^O NMR data for 1,3‐dioxaalkanes. Many of the compounds are new and together with the known compounds measured under similar conditions they constitute a well documented compilation of spectral data suitable for addition to databases and assistance in chemical shift calculations. Copyright © 2001 John Wiley & Sons, Ltd.