𝔖 Bobbio Scriptorium
✦   LIBER   ✦

195Pt NMR studies on monomer and dimer complexes. Observation of PtPt coupling constants

✍ Scribed by J. Soulié; J. Y. Lallemand; R. C. Rao


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
341 KB
Volume
12
Category
Article
ISSN
0749-1581

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Various platinum complexes have been studied by ^195^Pt FT NMR. Long range J(^31^P^195^Pt) and J(^195^Pt^195^Pt) are observed in dinuclear complexes. The value of ^1^J(^31^P^195^Pt) in monomeric and dimeric complexes is shown to depend mainly upon the Pt—P bond length.


📜 SIMILAR VOLUMES


Conformational studies on pyranoid sugar
✍ Philippe L. Durette; Derek Horton 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 English ⚖ 675 KB

## Abstract Proton spin‐spin coupling values measured for a wide range of tetrasubstituted tetrahydropyran ring‐systems obtained from aldopentopyranose sugars have been correlated with values calculated from a generalized version of the Karplus equation which takes into account the electronegativit

Solvent Effects on 195Pt and 205Tl NMR C
✍ Jochen Autschbach; Boris Le Guennic 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB 👁 1 views

## Abstract The ^295^Pt and ^205^Tl NMR chemical shifts of the complexes [(NC)~5~PtTl(CN)~__n__~]^__n__−^ __n__=0–3, and of the related system [(NC)~5~PtTlPt(CN)~5~]^3−^ have been computationally investigated. It is demonstrated that based on relativistically optimized geometries, by applying an

Spectroscopic studies on olefins. VII–pr
✍ Frans H. A. Rummens; Christian Simon; Claude Coupry; Nicole Lumbroso-Bader 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 702 KB

## Abstract The proton spectra of the compounds propene (1) and 3‐methylbutene‐1 (2) have been measured in various solvents and, as neat liquids, at variable temperature. The effects of solvent and temperature on 1 are found to be small, but not negligible. The effect of temperature on the coupling