191. Primary photochemical reactions. Part IV. Decomposition of methyl ethyl ketone and methyl butyl ketone

Kinetics and thermochemistry of the gas

Kinetics and thermochemistry of the gas phase reaction of methyl ethyl ketone with iodine. II. The heat of formation and unimolecular decomposition of 2-iodo-3-butanone

✍ Richard K. Solly; David M. Golden; Sidney W. Benson 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 698 KB

Equilibrium constants for the reaction CH,COCH,CH, + I, + CH,COCHICH, + HI have been computed to fit the kinetics of the reaction of iodine atoms with methyl ethyl ketone. From a calculated value of S,O,,(CH,COCHICH,) = 93.9 f 1.0 gibbs/mole and the experimental equilibrium constants, AHY(CH,COCHICH