1,9-Stereocontrol from 1,7-induction using an allylstannane followed by an Ireland-Claisen rearrangement
β Scribed by Ella-Maria Moffatt; Eric J Thomas
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 783 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
The relative configurations of 1,8-stereogenic centres can be controlled by coupling the tin(IV) chloride promoted reactions of aldehydes with 4-alkoxypent-2-enylstannanes, which proceed with excellent 1,5-induction, with an Ireland-Claisen rearrangement: this approach has been used to complete a di
The relative configurations of 1,8-stereogenic centres can be controlled by coupling the tin(IV) chloride promoted reactions of aldehydes with 4-alkoxypent-2-enylstannanes, which proceed with excellent 1,5-induction, with a 2,3-Wittig rearrangement: this approach has been used to complete a diastere