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19-(R)- and 19-(S)-Hydroxydihydrokoumine from Gelsemium elegans

✍ Scribed by Long-Ze Lin; Geoffrey A. Cordell; Chao-Zhou Ni; Jon Clardy


Book ID
103338810
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
373 KB
Volume
29
Category
Article
ISSN
0031-9422

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Quassiols A were synthesized enantioselectively by using baker's yeast reduction and asymmetric dihydroxylation, but their optical properties were not identical to that of natural quassiol A. Stereostructure of natural quassiol A was proposed.