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183W31P spin-spin coupling in octahedral complexes

✍ Scribed by S.O. Grim; W. McFarlane; D.A. Wheatland

Book ID
107768341
Publisher
Elsevier Science
Year
1966
Weight
103 KB
Volume
2
Category
Article
ISSN
0020-1650

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📜 SIMILAR VOLUMES

A reversal of the sign of the 183W-19F s
A reversal of the sign of the 183W-19F spin-spin coupling constant in octahedral tungsten(VI) derivatives
✍ W. McFarlane; A. Noble; J. Winfield 📂 Article 📅 1970 🏛 Elsevier Science 🌐 English ⚖ 165 KB

In contrast with the behaviour of many coupling constants. lJ(19%-19~) can change sign. without an accompanying change in the valence of tungsten: the two W-F coupling constants have the same sign in MeOWF5 and related compounds, but they have opposite signs in the WOF< anion.