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18-crown-6: a strong complexing agent for alkali metal cations

✍ Scribed by R.N. Greene


Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
248 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis


In 1967 C. J. Pedersen reported that macrocycllc polyethers -"Crown"


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Tris(3,6-dioxaheptyl)amine: A superior c
✍ Ajay K. Bose; Pietro Mangiaracina πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 267 KB

Commercially available tris(3,6\_dioxaheptyl)amine (TD&1) is an effective phase transfer catalyst for reactions with sodium-potassium alloy in tetrahydrofuran. Deoxygenation of acetates, dehalogenation, and hydrolysis of tosylates and mesylates proceed in high yield. The use of a deuterated alcohol