## Abstract __Trans__‐Cinnamaldehydes (CAs) or __o__‐, __m__‐ and __p__‐X‐(__E__)‐3‐phenylpropenals; (X = Cl or Br) were synthesized and their ^1^H, ^13^C and ^17^O NMR spectra were measured, assigned and analysed. The long‐range benzylic couplings are discussed in terms of the conformational chara
17O NMR studies on (E)-3-arylidenechromanone and -flavanone derivatives
✍ Scribed by Gábor Tóth; András Simon; Albert Lévai; Hanspeter Kählig; Hermann Kalchhauser
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 94 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.877
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✦ Synopsis
Abstract
^17^O NMR data for some 3‐arylidenechromanones and ‐flavanones are discussed in terms of mesomeric and steric substituent interactions. The transmission of long‐range substituent effects was studied. ^17^O NMR chemical shifts were correlated with Hammett σ~p~^+^ values for 4′‐substituted derivatives. Copyright © 2001 John Wiley & Sons, Ltd.
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## Abstract ^17^O NMR was used to probe the steric and electronic substituent effects in furan‐2,3‐dione derivatives. The carbonyl ^17^O chemical shifts correlate with Hammett constants and IR carbonyl stretching band frequencies for 5‐(__para__‐substituted‐phenyl)furan‐2,3‐diones.
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## Abstract Isomeric ring substituted monofluoro‐(__E__)‐3‐phenylpropenals (cinnamaldehydes) were synthesized in order to provide, with the NMR‐active ^19^F nucleus, an insight into the influence of substituents and the transmission of electronic effects between the aromatic ring and the side‐chain