17O NMR Spectroscopy of Organic Compounds Containing the -O—O- Group
✍ Scribed by Giovanni Cerioni; Francesca Mocci
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 18 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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The mechanism of ozonolysis was revisited with the use of bridge of the secondary ozonides is carrying the 17 O label. This is contrary to results reported earlier and confirms the 17 O-NMR spectroscopy. In a crossover experiment with 17 Olabelled benzaldehyde and the ozonides of styrene and Criegee
The 17O shift values of para-substituted benzoyl compounds (X = H, COOEt, Br, Cl, F, p-YC 6 H 4 COX CF 3 , SEt, OCOAr, OH, O-Na', were measured. The 17O shielding values d(17O) of these and other aryl-NH 2 ) unsubstituted benzoyl compounds (Y = H) follow the electron-donating power of X (resonance),