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1,7-Electrocyclisations of stabilised azomethine ylides

✍ Scribed by Miklós Nyerges; Andrea Virányi; Áron Pintér; László Tőke

Book ID
104252769
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
156 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

Ester-stabilised a,b:g,d-unsaturated azomethine ylides 9 were generated by the deprotonation method from isoquinolinium salts 8. 1,7-Electrocyclisation of these dipoles followed by a 1,5-hydrogen shift, gives tetrahydro [5,6]azepino[2,1a]isoquinolines 10.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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