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17. Aconitine. Part I. Oxonitin and the oxidation of aconitine with nitric acid and chromic acid

✍ Scribed by Lawson, Alexander

Book ID
121331754
Publisher
The Royal Society of Chemistry
Year
1936
Weight
376 KB
Category
Article
ISSN
0368-1769

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Preparation of adipic acid by oxidation
Preparation of adipic acid by oxidation of cyclohexanol and cyclohexanone with nitric acid: Part I. Reaction mechanism
✍ W. J. van Asselt; D. W. van Krevelen πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 662 KB

## Abstract The oxidation of cyclohexanol with nitric acid to adipic acid proceeds via two stable intermediates known from the literature^1^ viz. 6‐hydroxyimino‐6‐nitro hexanoic acid and the hemihydrate of 1,2‐cyclohexanedione, two substances forming beside each other in a given ratio. This ratio c