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1,6-Methano[10]annulene has a Delocalized Structure in S0 and S1: High-Resolution Spectroscopy in a Supersonic Jet

✍ Scribed by Reinhold Seiler; Bernhard Dick


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
84 KB
Volume
40
Category
Article
ISSN
0044-8249

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✦ Synopsis


The synthesis of the potassium salt was analogous to that of the compound 2, with a stoichiometric amount of potassium hydroxide instead of tetra-n-butylammonium hydroxide. Green crystals were isolated by filtering immediately after cooling the autoclave to room temperature. Yield (based on the solvent free compound): 0.36 g (0.084 mmol), 41 %. Elemental analysis calcd (%, based on the solvent free compound) for