1,6-Di-O-phenylsulfonyl-D-mannitol. Its Preparation and Use in the Synthesis of Some Derivatives of D-Mannitol
โ Scribed by Skinner, Glenn S.; Henderson, Loran A.; Gustafson, Carl G.
- Book ID
- 111953987
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 412 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
1,2:5,6-Di-0-isopropylidene-o-mannitol (1) is the most important source of o-glyceraldehyde derivatives which are usedIe widely in synthesis. The formation of 1 from o-mannitol (2) has been studied severally"5. All of the syntheses require the separation of 1 from the accompanying 1,2:3,4:5,6\_tria
Three different methods of acetonation of D-mannitol using (a) acetone and zinc chloride, (6), 2,2\_dimethoxypropane, l,Zdimethoxyethane, and tin(I1) chloride, and (c) 2-methoxypropene, N, N-dimethylformamide, and p-toluenesulfonic acid were studied in detail and compared, using gas-liquid chromatog
The cyclopolymerization of 3,4-di-O-allyl-1,2 : 5,6-dianhydro-D-mannitol ( 1) was carried out using BF 3 rOEt 2 and t-BuOK. The polymer obtained by the polymerization with BF 3 rOEt 2 mainly consisted of (1r6)-bonded 3,4-di-O-allyl-2,5-anhydro-Dglucitol as the five-membered constitutional repeating