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1,6-Asymmetric Induction During the Conjugate Addition of Arylcopper Reagents to Chiral Sulfinyl-Substituted Pyrrolyl α,β-Unsaturated Enones.

✍ Scribed by Yoshitsugu Arai; Kimio Ueda; Jianhua Xie; Yukio Masaki


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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Recoverable Chiral Sulfoxide: Remote Asymmetric Induction in Lewis Acid-Promoted Diels-Alder Reaction of Chiral Sulfinyl-Substituted Pyrrolyl α,β-Unsaturated Enones. -Stereoselective Diels-Alder reactions in the presence of AlCl 3 or Sm(O-Tf) 3 yield 96-99% of endo-enriched product mixtures which a