๐”– Bobbio Scriptorium
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1,6-Anhydroglucose in organic synthesis; preparation of fragments suitable for natural product synthesis

โœ Scribed by Paul J. Hodges; Garry Procter


Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
191 KB
Volume
26
Category
Article
ISSN
0040-4039

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Exploitation of molecular symmetry can greatly improve the efficiency of syntheses. The symmetry embedded in the centrosymmetric AB dioxepane fragment of hemibrevetoxin B was exploited for the first time in the preparation of an established intermediate in its total synthesis. Desymmetrization of th