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1,6-Anhydro-β- l -hexopyranoses as Potent Synthons in the Synthesis of the Disaccharide Units of Bleomycin A 2 and Heparin

✍ Scribed by Hung, Shang-Cheng; Thopate, Shankar R.; Chi, Fa-Chen; Chang, Shu-Wen; Lee, Jinq-Chyi; Wang, Cheng-Chung; Wen, Yuh-Sheng


Book ID
120215163
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
45 KB
Volume
123
Category
Article
ISSN
0002-7863

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1,6-Anhydro-β-l-hexopyranoses as valuabl
✍ Shang-Cheng Hung; Cheng-Chung Wang; Shu-Wen Chang; Chien-Sheng Chen 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 89 KB

1,6-Anhydro-b-L-hexopyranoses as valuable building blocks toward the synthesis of L-gulosamine and L-altrose derivatives via the regioselective triflation and benzoylation of 1,6-anhydro-b-L-idopyranose followed by S N 2 substitution with various nucleophiles as key steps is described here.