16-(3-Pyridylmethylene)androst-4-ene-3,17-dione
✍ Scribed by Vasuki, G. ;Parthasarathi, V. ;Ramamurthi, K. ;Dubey, S. ;Jindal, D. P.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 183 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, C 25 H 29 NO 2 , ring A adopts a slightly distorted half-chair conformation, while rings B and C are in chair conformations. The ®ve-membered ring D adopts a 13,14-half-chair conformation. The 3-pyridyl ring has an E con®guration with respect to the carbonyl group at position 17. The crystal structure is stabilized by weak intra-and intermolecular CÐHÁ Á ÁO interactions and van der Waals forces.
📜 SIMILAR VOLUMES
In the title compound, C 29 H 37 NO 4 Á0.46H 2 O, rings A and C adopt chair conformations and ring B is in a half-chair conformation. The ®ve-membered ring D adopts an envelope conformation. The crystal structure is stabilized by weak intermolecular CÐHÁ Á ÁO interactions and van der Waals forces.
Different mutants of the catabolism of androst-4-ene-3,17-dione were produced in Nocardia restricta by action of y-rays and nitrosoguanidine. These selected mutants (acetate+-undrost-4-ene-3,17-dione-) are hexanoate-. Their behaviour is identical to the mutants selected as hexanoateacetatet which ar
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v