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15N solid-state NMR studies of platinum ammine complexes

โœ Scribed by Patrick J. Barrie; Elliot J.W. Austin; Adriana Barbieri; Robin J.H. Clark


Book ID
108328571
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
631 KB
Volume
264
Category
Article
ISSN
0020-1693

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15N-NMR. and 31P-NMR. Studies of palladi
โœ Herbert Motschi; Paul S. Pregosin; Luigi M. Venanzi ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 561 KB

NH2(CH&CH3 and (for Pt) C2H4. For both metals, the NMR. parameters depend on the trans-influence of the ligand L. The values 1J(195Pt, 15N) vary from 138 to 336 Hz and can be shown to correlate with the values 1J(195Pt, 31P) in the complexes trans-[PtCl,(PBu!j)L]. There is a linear relation between