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15N Nuclear magnetic resonance of some pyrazines, 1,2,4-triazines and their N-oxides. Correlation and interrelationship of 15N with 13C chemical shifts of π-deficient heterocyclic systems

✍ Scribed by Misa V. Jovanovic


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
459 KB
Volume
40
Category
Article
ISSN
1386-1425

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✦ Synopsis


The 15Nchemical shifts of a number of pyrazines, 1,2,4-triazines, and their N-oxides are reported. The shielding effects of a substituent ortho to a ring nitrogen on that nitrogen atom depend on the ITdeficiency of the heterocyclic ring. These n-deficiency values are related to ortho "C chemical shifts in