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15N chemical shifts and one bond 15N1H coupling constants in simple amides

✍ Scribed by J. P. Marchal; D. Canet

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
294 KB
Volume
15
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

An indirect method is employed for determining the ^15^N parameters at the natural abundance level in a series of simple acyclic and cyclic amides. The one bond coupling constant, ^1^J(^15^N^1^H), and the ^15^N chemical shift are measured as a function of the carbonyl substituent group or the ring size and the nature of the solvent (CCl~4~ or H~2~O). These ^15^N parameters are related to the amide bond structure, the nitrogen configuration and possible intermolecular hydrogen bonding (amide‐amide or amide‐water).

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