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15N, 119Sn, and 207Pb nuclear magnetic resonance of monomeric tin(II) and lead(II) amides

โœ Scribed by Bernd Wrackmeyer


Publisher
Elsevier Science
Year
1985
Weight
251 KB
Volume
61
Category
Article
ISSN
0022-2364

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Solid-state (CP-MAS) 29Si-, 119Sn and 20
โœ Bernd Wrackmeyer; Angelika Sebald; Lawrence H. Merwin ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 397 KB

## Abstract Solidโ€state CPโ€MAS ^29^Siโ€, ^119^Snโ€ and ^207^Pb NMR spectra of bis(pentamethylcyclopentadienyl)โ€silicon (1) โ€tin (2) and โ€lead (3) were measured. The spectra reflect the gross structural features, known from xโ€ray analyses for 1โ€“3. In 1a, which has a parallel arrangement of the Me~5~C~

Sign determination of coupling constants
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## Abstract Heteronuclear double and triple resonance experiments of the type ^1^H{X} (X = ^31^P, ^199^Hg, ^207^Pb), ^13^C{^1^H, ^31^P}, ^29^Si{^1^H, ^31^P}, ^207^Pb{^1^H, ^31^P}, pseudoโ€triple resonance experiments [e.g. ^13^C{^1^H(^199^Hg)}, ^207^Pb{^1^H(^13^C)}], together with twoโ€dimensional (2